![]() METHOD FOR STABILIZING A TECHNICAL FILLER
专利摘要:
The invention relates to a method of stabilizing a technical embankment, including the layer of the form of this embankment. This process is remarkable in that it comprises the following steps consisting of: selecting fluvial sediments 90% of the particles having a particle size of less than or equal to 250 μm and comprising a mixture of limestone and clay at a rate of at least 40% by weight of the total of said river sediments, the clay representing at least 20% by weight of said river sediments, - heating them to bring them to a temperature between 600 ° C and 850 ° C, for a period of time between 1 hour and 6 hours, - cool to bring them to a temperature below 100 ° C, in a time less than or equal to 1 hour, and thus obtain a stabilizing additive, - and mix said additive to a fine soil , so that in the presence of moisture, one obtains the stabilization of said technical backfill. 公开号:FR3017398A1 申请号:FR1450961 申请日:2014-02-07 公开日:2015-08-14 发明作者:Francois Thery;Baptiste Anger 申请人:Electricite de France SA; IPC主号:
专利说明:
[0001] GENERAL TECHNICAL FIELD The invention lies in the field of civil engineering and more specifically technical embankments. [0002] The present invention more specifically relates to a method of stabilizing a technical embankment, including the layer of the form of this embankment. STATE OF THE ART In the field of civil engineering, it is necessary to realize various road infrastructures and assimilated, namely roads, pedestrian routes, paths, bike paths, car parks and landscaped embankments (roadside ). These various infrastructures are formed on embankments, called "technical", and more particularly for the roads, on so-called "road" embankments. It should be noted that technical embankments are also constructed when harbor dykes or seawall protection or flood protection dams are constructed. Referring to Figure 1 attached, a schematic cross-sectional view of a road can be seen. The latter conventionally comprises from the bottom upwards, the natural ground A (only the upper part of the earthworks being represented), a layer of form B, a foundation layer C, a base layer D and a wearing course In general, a road must withstand various stresses, in particular those due to traffic, and must ensure the diffusion of the forces induced by this same traffic in the natural terrain A. Its dimensions and the number and thickness of its layers depend mainly on two fundamental factors: traffic and the bearing capacity of the soil. It is mainly the B-shaped layer that must provide a certain lift for the transmission of forces in the natural terrain A. [0003] In the case of pedestrian routes, paths and cycle paths, this guarantee of lift is of a lower level but remains nevertheless an important parameter. As a result, the recommendations concerning the lift of their shape layer are quite close to those of the roads. [0004] The realization of all these technical embankments and the layers that constitute them leads to the consumption of a large volume of materials. As a result, in the context of a saving of materials, the noblest are reserved for the upper layers C and D and the least noble for the layer of form B. Thus, it is possible to use so-called "fine" soils in the form layer. These fine soils are defined in the Guide to Road Excavations, embankments and layers of shapes, fascicles I and II, SETRA-LCPC GTR 2nd edition July 2000, as part of class A or class B, and requiring treatment to be used. These fine soils may for example be dam sediments. The use of some fine soils for the construction of shaped layers, however, poses a problem of mechanical quality of the structures obtained. To remedy this, fine soils are stabilized by mixing with binders, such as lime, cement or road hydraulic binders. [0005] However, the manufacture of cement and lime requires the exploitation of deposits of limestone and clay. In a context of depletion of raw materials, the manufacture in France and Europe of this type of product becomes delicate. To this must be added the regulatory difficulties to obtain the opening of new careers. [0006] In addition, their production is both energy intensive and relatively expensive. For example, the manufacture of cement and lime require the implementation of baking processes of the raw material, respectively at temperatures of about 1450 ° C and about 1000 ° C. [0007] In order to save cement or lime, it is known to replace them in part with alternative pozzolanic materials which are mainly derived from natural pozzolans or waste materials, such as fly ash from coal or iron slags from the iron and steel industry. EP 1 441 020 illustrates this solution. [0008] By "pozzolanic material" is meant a material which has the ability to harden when mixed with lime or cement in the presence of water. However, coal fly ash and steel slag 5 are likely to be lacking in France as a result of the reduction in the number of boilers using coal as fuel and the reduction of the iron and steel fleet. PRESENTATION OF THE INVENTION The object of the invention is therefore to solve the aforementioned drawbacks of the state of the art. It aims in particular to provide a method of stabilizing a technical embankment, including the layer of the form of this backfill, which 15 allows to reduce the amount of lime or cement used, or even to do without and also not to use coal fly ash or iron slags. The invention also aims to reduce the costs compared to known methods of the state of the art using cement or lime. To this end, the invention relates to a method for stabilizing a technical embankment, in particular the shape layer thereof. According to the invention, this process comprises the following steps: selecting fluvial sediments 90% of the particles have a particle size less than or equal to 250 [Inn and which comprise a mixture of limestone and clay at a rate of at least 40% by weight of the total of said river sediments, the clay representing at least 20% by weight of said river sediments, heating said sediments to bring them to a temperature between 600 ° C and 850 ° C, for a period of between 1 hour and 6 hours, - cooling these sediments to bring them to a temperature below 100 ° C, in a time less than or equal to 1 hour, and thus obtaining a stabilizing additive, - and mixing said stabilizing additive to a fine soil, so that in the presence of moisture, one obtains the stabilization of said technical backfill. Thanks to these characteristics of the invention, it is thus possible to valorize fluvial sediments, for example dam sediments, by using them as secondary raw material. In addition, these river sediments exist in large volumes and dam sediments inevitably accumulate in the reservoirs of hydraulic structures where they are easier to collect. In addition, sediments have the advantage of not being dependent on the techno-economic hazards of steelmaking (steelmaking) or of electricity production (fly ash). Finally, the temperatures of 600 ° C. to 850 ° C. used in this process are much lower than those used for the manufacture of cement, used in the state of the art as an additive for making embankments. This results in energy savings and manufacturing costs. According to other advantageous and nonlimiting features of the invention, taken alone or in combination: the stabilizing additive is mixed with the fine soil, at a rate of 2% 20 to 15% by weight of additive and 85% 98% by weight of fine soil; the stabilizing additive is mixed with the fine soil and with an additional reagent, at 2% to 15% by weight of a mixture of stabilizing additive and additional reagent and 85% to 98% by weight of fine soil; The additional reagent is lime; the additional reagent is cement; during the heating of the sediments, the rise in temperature is carried out at the rate of 5 ° C / min at 15 ° C / min; the sediments are put in dry powder form or semi-wet granules or sections of pressed pulp, extruded and then heated; after the cooling step and before being mixed with the fine soil, the stabilizing additive is ground so that it has particles less than or equal to 250 [Inn; after the cooling step and before being mixed with the fine soil, the stabilizing additive is ground so that it has particles less than or equal to 100 [Inn; and sediment heating is carried out in rotary kilns. [0009] PRESENTATION OF THE FIGURES Other features and advantages of the invention will appear from the description which will now be made with reference to the accompanying drawing (Figure 1) which shows a schematic cross sectional view of a road. DETAILED DESCRIPTION The method of stabilizing a technical embankment, according to the invention, comprises a first step which consists in selecting the river sediments which will allow the manufacture of a stabilizing additive. By "river sediments" is meant sediments likely to be harvested in river beds, for example by dredging, as well as sediments which will accumulate at the foot of the dams. Depending on the watersheds where the hydraulic structures (dams) are located and those where the sediments are taken, it is possible to extract sediments of different mineralogical natures. The sediments which, on the one hand, comprise at least 20% by weight of clay and at least 40% by weight of this mixed clay and limestone and, on the other hand, have a particle size of less than or equal to at 250 [Inn for 90% of the particles constituting them. In the remainder of the description and the claims, the term "clay" refers to "clay in the mineralogical sense", that is to say belonging to the family of phyllosilicates and not the clay in the granulometric sense. It will be noted that at the dam head, fine sediments generally have a grain size corresponding to the above-mentioned one. The particle size is checked by sieving or laser granulometry. [0010] The selection of fine sediments, whose particle size is less than 250 [Inn, makes it possible to have materials, in particular clay and limestone, which are very reactive during the subsequent firing stage. In addition, because these sediments are extremely thin, it is not necessary to grind them for use, which generates energy and cost savings. Having at least 40% by weight of the mixture of clay and limestone and at least 20% by weight of clay makes it possible to have a minimum amount of clay which, in the presence of lime, makes it possible to develop a sufficient cohesion of the clay. technical embankment. [0011] In order to verify the above percentages, fluvial sediment samples are taken and analyzed by x-ray diffraction. A second step of the process consists in heating the selected sediments, at a temperature between 600 ° C and 850 ° C, during a duration preferably between 1 hour and 6 hours. This means that the aforesaid temperature is maintained during this time. The sediments are preferably heated to 5 ° C per minute at 15 ° C per minute. The sediment heating has the effect of destabilizing the clay and transforming it into pozzolanic material and transforming the limestone into quicklime. The heating temperature and the rate of rise in temperature are optimized on the basis of results obtained from analyzes carried out on samples of the retained sediments, these analyzes being, on the one hand, a thernnodifferential analysis (DTA) and, on the other hand, on the other hand, a thermogravimetric analysis (ATG) which makes it possible to verify the nature of the material obtained by heating. Note that below 600 ° C, the clay is not converted into pozzolanic material, and above 850 ° C, the crystals that have been disrupted by heating may reorganize, so that no pozzolanic material is obtained. Advantageously, the heating of the selected sediments at a temperature of the order of 600 ° C to 850 ° C also makes it possible to calcine the part of organic matter contained in the original sediments. However, this organic material, in the absence of such a heat treatment would be detrimental to the realization of a technical embankment, since it would cause in it a swelling or a decline in its mechanical properties. [0012] In addition, if metallic pollutants are present in the selected sediments, cooking can stabilize them as a mineral phase and also destroy some organic pollutants. The heating is preferably carried out in rotary kilns, within which they are heated. These ovens have the advantage of allowing continuous production. These sediments can be introduced into the oven, either in dry powder form, or in the form of semi-wet granules preferably of about 1 cm in diameter, or in the form of extruded strands previously formed from the powdered sediment. A third step of the process then consists in rapidly cooling the previously heated sediments, so as to bring them to a temperature below 100 ° C, preferably within one hour. This rapid cooling makes it possible in particular to preserve the pozzolanic properties of the clay. At the end of the heating and cooling steps, the stabilizing additive obtained may have formed amalgams. If necessary, an optional fourth step may be added to the method. It involves grinding the dried sediments obtained, so as to obtain particles whose particle size is less than or equal to 250 [Inn, preferably less than or equal to 100 [Inn. This makes it possible to obtain an even more reactive stabilizing additive. The stabilizing additive is therefore a ready-to-use product which comprises a pozzolanic material and lime and which cures in the presence of moisture. Before use, this stabilizing additive must be kept dry. Advantageously, the obtained stabilizing additive is tested for the quality of its pozzolanicity, i.e., its ability to cure when mixed with water. This verification can be carried out by measuring an activity index or by a Chapelle test, tests that must be equivalent to the results obtained for a metakaolin of standard NF P 18 513. According to a fifth step of the process according to the According to the invention, the stabilizing additive obtained is mixed with a fine soil so as to produce a technical backfill and in particular a layer of shape of this backfill. [0013] For this purpose, the stabilizing additive is advantageously mixed with the fine soil in a proportion of 2% to 15% by weight of additive and 85% to 98% by weight of fine soil. By "fine soil" is meant a soil which meets the definition of the above-mentioned road earthworks guide as being class A, that is to say having a sieve at 80 μm greater than 35% and whose particles have a diameter. maximum (Dmax) less than 50mm, for example river sediments which themselves have not undergone the aforementioned heating treatment. This mixing can be carried out by a kneading operation, in a central road. [0014] According to another embodiment variant, the stabilizing additive is spread directly on the ground and kneaded on site using a machine known under the name "ROTAVATOR" (registered trademark). Finally, it is necessary to incorporate water in the mixture comprising the fine soil and the stabilizing additive. [0015] According to an optional alternative embodiment of the invention, it is sometimes necessary to add to the stabilizing additive, an additional reagent, such as lime or cement, before mixing it with fine soil. In this case, the additive stabilizer and reagent mixture still represents 2 to 15% by weight, the remaining 85% to 98% by weight consisting of fine soil. [0016] The addition of lime, as an additional reagent, can be done for example if the lime content of the stabilizing additive is not high enough. However, this addition will be less than in the total absence of the stabilizing additive according to the invention, which reduces costs. Whatever the variant embodiment chosen (with or without additional reagent), it is considered that the abovementioned percentages make it possible to obtain good mechanical strength of the mixture, after it has been brought into the presence of moisture since, after 28 days of hardening, the resistance is greater than 1 MPa. According to another variant embodiment, it will be noted that the stabilizing additive obtained can also be used in the manufacture of cement. To make cement, it is necessary to use a crushed clinker to which fly ash of coal and steel slag is often added, this clinker being produced by means of energy-intensive heating processes, since they require reach temperatures of 1450 ° C. The stabilizing additive according to the invention can thus be used in the manufacture of cement to replace a part of the clinker powder. [0017] Finally, this stabilizing additive can also be used for the manufacture of concrete, in substitution for a portion of the cement powder.
权利要求:
Claims (10) [0001] REVENDICATIONS1. A method of stabilizing a technical embankment, in particular of the layer of this embankment, characterized in that it comprises the following steps: - selecting river sediments 90% of the particles have a particle size less than or equal to 250 [Inn and which comprise a mixture of limestone and clay in a proportion of at least 40% by weight of the total of said river sediments, the clay representing at least 20% by weight of said river sediments, - heating said sediments so as to bring them to a temperature between 600 ° C and 850 ° C for a period of between 1 hour and 6 hours, - cool these sediments to bring them to a temperature below 100 ° C, in a time less than or equal to 1 hour, and thus obtain a stabilizing additive, - and mixing said stabilizing additive to a fine soil, so that in the presence of moisture, one obtains the stabilization of said technical backfill. [0002] 2. Method according to claim 1, characterized in that the stabilizing additive is mixed with the fine soil, in a proportion of 2% to 15% by weight of additive and from 85% to 98% by weight of fine soil. . [0003] 3. Method according to claim 1, characterized in that the stabilizing additive is mixed with the fine soil and with an additional reagent, in a proportion of 2% to 15% by weight of a mixture of stabilizing additive and additional reagent and from 85% to 98% by weight of fine soil. 25 [0004] 4. Method according to claim 3, characterized in that the additional reagent is lime. [0005] 5. Method according to claim 3, characterized in that the additional reagent is cement. [0006] 6. Method according to one of the preceding claims, characterized in that during the heating of the sediments, the temperature rise is performed at a rate of 5 ° C / nrin at 15 ° C / nrin. [0007] 7. Method according to one of the preceding claims, characterized in that the sediments are put in dry powder form or semi-wet granules or sections of pressed pulp, extruded and heated. [0008] 8. Method according to one of the preceding claims, characterized in that after the cooling step and before being mixed with the fine soil, the stabilizing additive is ground so that it has particles less than or equal to 250 [Inn. [0009] 9. A method according to claim 8, characterized in that after the cooling step and before being mixed with the fine soil, the stabilizing additive is ground so that it has lower or equal particles. at 100 [Inn. [0010] 10. Method according to one of the preceding claims, characterized in that the heating of the sediment is carried out in rotary kilns. 15
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同族专利:
公开号 | 公开日 WO2015117818A1|2015-08-13| FR3017398B1|2017-06-23|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 FR2471444A1|1979-12-03|1981-06-19|Lonza Werke Gmbh|PROCESS FOR STABILIZING THE SOIL WITH LIME| US8387688B2|2006-09-14|2013-03-05|Ernest E. Carter, Jr.|Method of forming subterranean barriers with molten wax| WO2011159154A1|2010-06-16|2011-12-22|Stichting Energieonderzoek Centrum Nederland|Pyrolysis of lignin| CN105862560B|2014-05-26|2018-02-02|江苏鼎泰工程材料有限公司|The method repaired at the Bridge back wall of environmentally safe road pavement| CN104047213B|2014-05-26|2016-05-25|江苏鼎泰工程材料有限公司|A kind of method for repairing road surface that can solve hard stratum and Soft Soil Layer sinking speed difference| CN105350418B|2015-12-04|2018-08-03|中国铁道科学研究院铁道建筑研究所|Subgrade strengthening method| CN107938456B|2017-11-29|2020-10-09|宁波衡华园林建设有限公司|Construction method for filling river channel| CN113417183A|2021-07-26|2021-09-21|招商局重庆交通科研设计院有限公司|Red clay roadbed and construction method|
法律状态:
2015-08-14| EXTE| Extension to a french territory|Extension state: PF | 2016-02-29| PLFP| Fee payment|Year of fee payment: 3 | 2017-02-28| PLFP| Fee payment|Year of fee payment: 4 | 2018-02-26| PLFP| Fee payment|Year of fee payment: 5 | 2020-02-18| PLFP| Fee payment|Year of fee payment: 7 | 2021-02-11| PLFP| Fee payment|Year of fee payment: 8 | 2022-01-13| PLFP| Fee payment|Year of fee payment: 9 |
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申请号 | 申请日 | 专利标题 FR1450961A|FR3017398B1|2014-02-07|2014-02-07|METHOD FOR STABILIZING A TECHNICAL FILLER|FR1450961A| FR3017398B1|2014-02-07|2014-02-07|METHOD FOR STABILIZING A TECHNICAL FILLER| PCT/EP2015/051061| WO2015117818A1|2014-02-07|2015-01-21|Technical embankment stabilization method| 相关专利
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